Aluminylation: a generalizable route towards low-valent aluminum under moderate conditions with controlled product nuclearity through precursor design

Key Points

• The aim is to establish a method for synthesizing low-valent aluminum complexes with specific characteristics based on precursor design.
• Utilized aluminylation technique
• Examined substrate identity for reactivity
• Analyzed aluminum speciation effects on product structure
• Successfully produced low-valent aluminum complexes with controlled nuclearity
• Demonstrated tunability in heterolepticity based on substrate variations

Abstract