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Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of Cp(iPr3P)Ru(NCCH3)2+ has the advantages that it is 1,4-regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex CpRu(NCCH3)3+ catalyzes the two-hydrogen-atom reduction of phenanthroline by HSiMe2Ph/water.
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Gutsulyak et al. (Wed,) studied this question.
www.synapsesocial.com/papers/6a028d5467f6ea5cc87548c9 — DOI: https://doi.org/10.1002/anie.201006135
Dmitry V. Gutsulyak
Art van der Est
Georgii I. Nikonov
Angewandte Chemie International Edition
Brock University
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